WARD CHEMICAL INC. CALCIUM CHLORIDE SOLUTION MATERIAL SAFETY DATA SHEET

Trade Name: Grade V1300 CALCIUM CHLORIDE (29%)

General Information



Company's Name: WARD CHEMICAL INC. 
Company's Street: 6015 - 103A STREET 
Company's City: EDMONTON 
Company's Province: Alberta 
Company's Country: Canada 
Company's Postal Code: T6H 2J2 
Company's Emerg Ph #: 780-940-1133 
Company's Info Ph #: 780-436-3780 
Date MSDS Prepared: 04MAR02 
Safety Data Review Date: 15 Mar08 

Ingredients/Identity Information

Ingredient: CALCIUM CHLORIDE
Percent: 29.0 +/- 0.50
NIOSH (RTECS) Number: EV9800000 
CAS Number: 10043-52-4 
OSHA PEL: NOT APPLICABLE 
ACGIH TLV: NOT APPLICABLE 
Other Recommended Limit: 10 MG/M3 (MFR) 
------------------------------------
Ingredients: Sodium Chloride/ Potassium Chloride
Percent: 1.5 - 2.5 
NIOSH (RTECS) Number: VZ4725000 
CAS Number: 7647-14-5 
OSHA PEL: NOT APPLICABLE 
ACGIH TLV: NOT APPLICABLE 
-------------------------------------
Ingredient: WATER
Percent: 69 - 71 
NIOSH (RTECS) Number: ZC0110000 
CAS Number: 7732-18-5 
OSHA PEL: NOT APPLICABLE 
ACGIH TLV: NOT APPLICABLE 

Physical/Chemical Characteristics

Appearance And Odor: CLEAR, ODORLESS 
Boiling Point: 230F,160C 
Vapor Pressure (MM Hg/70 F): SAME/H2*O 
Vapor Density (Air=1): 7-15@25C 
Specific Gravity: 1.37(20 C) 
Solubility In Water: COMPLETELY MISCIBLE 

Fire and Explosion Hazard Data

Flash Point: NOT APPLICABLE 
Lower Explosive Limit: N/A 
Upper Explosive Limit: N/A 
Extinguishing Media: NON-COMBUSTIBLE
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE
SCBA.
Unusual Fire And Expl Hazrds: NONE SPECIFIED BY MANUFACTURER.

Reactivity Data

Stability: YES 
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: METALS WILL SLOWLY CORR IN AQU SOLN. ALUMINUM(AND ITS
ALLOYS) AND YELLOW BRASS WILL BE ATTACKED BY CALCIUM CHLORIDE.
Hazardous Decomp Products: NOT APPLICABLE
Hazardous Poly Occur: NO 
Conditions To Avoid (Poly): NONE SPECIFIED BY MANUFACTURER.

Health Hazard Data

LD50-LC50 Mixture: ORAL(RAT)900-2100MG/KG 100% CACL 
Route Of Entry - Inhalation: YES 
Route Of Entry - Skin: NO 
Route Of Entry - Ingestion: NO 
Health Haz Acute And Chronic: EYE:MOD/SEVERE EYE IRRIT W/CORNEAL INJURY
MAY BE SLOW TO HEAL AT HIGH TEMPS, MATERIAL HAS MORE INTENSE EFTS AND
THERMAL BURNS POSSIBLE. SKIN:RPTD EXPOSURE MAY CAUSE SKIN IRRIT, EVEN
BURNS.MORE SEVERE RESPONSE IF CONFINED TO SKIN OR SKIN IS SCRATCHED/CUT.
INGEST: MAY CAUSE GI IRRIT OR ULCERATION. (SEE EFTS OF OVEREXP)
Carcinogenicity - NTP: NO 
Carcinogenicity - IARC: NO 
Carcinogenicity - OSHA: NO 
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: HEALTH HAZARDS: INHAL: MISTS MAY CAUSE
IRRITATION TO UPPER RESPIRATORY TRACT.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: EYES:IRRIGATE W/FLOWING WATER IMMED. AND CONT
FOR 15 MIN. CONSULT MD. SKIN:WASH OFF IN FLOWING WATER OR SHOWER.
INGEST:INDUCE VOMIT IMMED, BY GIVING 2 GLASSES OF WATER AND STICKING FINGER
DOWN THROAT. CALL MD.INHAL:REMOVE TO FRESH AIR.CONSULT MD. NOTE TO MD: IF
BURN IS PRESENT, TREAT AS ANY THERMAL BURN. AFTER DECONTAM. NO SPECIFIC
ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDMENT (SUPP DATA)

Precautions for Safe Handling and Use

Steps If Matl Released/Spill: FLUSH AREA W/PLENTY OF WATER. WALKING
SURFACES MAY REMAIN WET LONGER DUE TO MOISTURE BEING HELD BY SPILLED
MATERIAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: WASH AWAY WITH LARGE EXCESS OF WATER. KEEP OUT OF
DRINKING WATER SOURCES. COMPLY WITH LOCAL, STATE, AND FEDERAL REGULATIONS
Precautions-Handling/Storing: MAY SOMETIMES BE SHIPPED HOT, WHICH MAY
CAUSE THERMAL BURNS & INTENSE CHEM IRRIT OR BURN. AVOID EYE & PROLONGED
SKIN CONTACT.
Other Precautions: ALWAYS USE COOL WATER (TEMP less than 80F) WHEN DILUTING CALCIUM
CHLORIDE SOLUTION. HEAT DEVELOPED BY SOLUTIONS IS VERY HIGH DURING MIXING.
LEATHER CLOTHING & SHOES WILL BE DAMAGED BY CALCIUM CHLORIDE.

Control Measures

Respiratory Protection: CONSULT LOCAL/SAFETY HEALTH AUTHORITIES IF
ADDITIONAL GUIDANCE IS NECESSARY. THERE IS NO OSHA PEL OR ACGIH TLV FOR
CALCIUM CHLORIDE.
Ventilation: GENERAL AND/OR LOCAL EXHAUST TO CONTROL AIRBORNE LEVELS BELOW
EXPOSURE GUILDLINES.
Protective Gloves: IMPERVIOUS GLOVES AS REQUIRED (FP N). 
Eye Protection: CHEM GOGGLES/EYE WASH FOUNT IN IMMD AREA 
Other Protective Equipment: USE PROTECTIVE CLOTHING IMPERVIUOS TO THIS
MATERIAL,GLOVES,BOOTS,APRON OR FULL-BODY SUIT WILL DEPEND ON OPERATION.
Work Hygienic Practices: IF SKIN COMES IN CONTACT W/CONTAIM CLOTHING
REMOVE COTHING IMMED, WASH SKIN AREA W/SOAP & WATER, LAUNDER CLOTHING.
Suppl. Safety & Health Data: FIRST AID PROC: NOTE TO PHYSICIAN: SUPPORTIVE
CARE. TREATMENT BASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS
OF THE PATIENT.

Transportation Data

DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
Additional Trans Data: NOT REGULATED FOR TRANSPORTATION

Disposal Data

Disposal mustcomply with local environmental regulations.

Label Data

Label Required: NO 
Technical Review Date: 15Mar08 
Common Name: CALCIUM CHLORIDE BRINE SOLUTION  
Acute Health Hazard-Slight: X 
Contact Hazard-Severe: X 
Fire Hazard-None: X 
Reactivity Hazard-None: X 
Special Hazard Precautions: ACUTE:AVOID EYE AND PROLONGED SKIN CONTACT.
CAUSES SKIN BURNS. DO NOT GET ON SKIN AND CLOTHING. AVOID BREATHING MIST.
KEEP CONTIANER CLOSED. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. MAY CAUSE RESPIRATORY TRACT IRRITATION.DO NOT INGEST. MAY CAUSE
IRRITATION/ULERATION.CHRONIC: HAZARDS NOT DETERMINED.
Protect Eye: Y 
Protect Skin: Y 

Calcium Chloride (CaCl2)

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